Surface Activator Solution / Acid Dip Solution
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Revision Date: 10/23/2014
Date of issue: 10/23/2014 Version: 1.0
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Mixture
Product Name: Surface Activator Solution / Acid Dip Solution
Synonyms: Mineral Acid
1.2. Intended Use of the Product
Use of the Substance/Mixture: No use is specified.
1.3. Name, Address, and Telephone of the Responsible Party
Company
Gold Plating Services
378 North Main #112
Layton, UT 84041
T:(801) 546 6200
gold-plating.com
1.4. Emergency Telephone Number
Emergency Number : PERS (801) 629-0667 or (800) 633-8253
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 1A H350
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
Signal Word (GHS-US) | : Danger |
Hazard Statements (GHS-US) |
: H315 - Causes skin irritation. H319 - Causes serious eye irritation. H350 - May cause cancer (Inhalation). |
Precautionary Statements (GHS-US) | : P201 - Obtain special instructions before use. P264 - Wash hands, forearms and face thoroughly after handling. P280 - Wear protective gloves, eye protection, face protection, protective clothing. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P321 - Specific treatment (see Section 4). P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. |
2.3. Other Hazards
Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. If involved in a fire and thermal decomposition occurs, or other decomposition occurs corrosive, toxic, and acrid vapors may be released.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Name | Product Identifier | % (w/w) | Classification (GHS-US) |
Water | (CAS No) 7732-18-5 | 97 | Not classified |
Sulfuric acid | (CAS No) 7664-93-9 | < 3 | Skin Corr. 1A, H314 Eye Dam. 1, H318 Carc. 1A, H350 Aquatic Acute 3, H402 |
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
Inhalation: Move to fresh air. Keep at rest and in a position comfortable for breathing. Seek medical attention. Symptoms may be delayed.
Skin Contact: Remove/Take off immediately all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Wash contaminated clothing before reuse. Seek medical attention if irritation persists.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Obtain medical attention if irritation persists.
Ingestion: Rinse mouth thoroughly with water. Do NOT induce vomiting. Seek medical attention immediately.
4.2. Most Important Symptoms and Effects Both Acute and Delayed
General: Causes skin irritation. Causes serious eye irritation. May cause cancer.
Inhalation: Contact may cause immediate severe irritation progressing quickly to chemical burns. May cause pulmonary edema. Symptoms may be delayed.
Skin Contact: Causes skin irritation.
Eye Contact: Causes serious eye irritation.
Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Swallowing a small quantity of this material will result in serious health hazard.
Chronic Symptoms: Strong inorganic acid mists containing sulfuric acid are carcinogenic to humans. May cause cancer by inhalation.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If you feel unwell, seek medical advice (show the label where possible).
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable.
Explosion Hazard: Product is not explosive.
Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present.
Firefighting Instructions: Keep upwind. Use water spray or fog for cooling exposed containers.
Protection During Firefighting: Firefighters must use full bunker gear including NIOSH-approved positive-pressure self-contained breathing apparatus to protect against potential hazardous combustion and decomposition products.
Hazardous Combustion Products: Corrosive vapors. Acrid smoke and irritating fumes. Sulfuric acid will release sulfur oxides at high temperatures. Sulfur oxides are toxic.
Other Information: Do not allow the product to be released into the environment.
Reference to Other Sections
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Avoid all unnecessary exposure. Do not get in eyes, on skin, or on clothing. Do not breathe vapor, mist or spray.
6.1.1. For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel. Keep upwind.
6.1.2. For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Stop leak if safe to do so. Ventilate area. Eliminate ignition sources.
6.2. Environmental Precautions
Do not allow to enter drains or water courses. Prevent entry to sewers and public waters. Contact competent authorities after a spill.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for Cleaning Up: Ventilate area. Cautiously neutralize spilled liquid. Clear up spills immediately and dispose of waste safely. Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Collect absorbed material and place into a sealed, labeled container for proper disposal. Practice good housekeeping - spillage can be slippery on smooth surface either wet or dry.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Contact with metals may evolve flammable hydrogen gas. May be corrosive to metals. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Always wash your hands immediately after handling this product, and once again before leaving the workplace. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke in areas where product is used.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Observe all regulations and local requirements regarding storage of containers.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store away from oxygen and oxidizers. Storage areas should be periodically checked for corrosion and integrity. Keep only in original container. Incompatible Materials: Water, humidity. Alkaline solutions. Metals. Oxidizers. Reducing agents. Combustible materials.
7.3. Specific End Use(s)
No use is specified.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or the Mexican government.
Sulfuric acid (7664-93-9) | ||
Mexico | OEL TWA (mg/m³ | 1 mg/m³ |
USA ACGIH | ACGIH TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
USA OSHA | OSHA PEL (TWA) (mg/m³) | 1 mg/m³ |
USA NIOSH | NIOSH REL (TWA) (mg/m³) | 1 mg/m³ |
USA IDLH | US IDLH (mg/m³) | 15 mg/m³ |
Alberta | OEL STEL (mg/m³) | 3 mg/m³ |
Alberta | OEL TWA (mg/m³) | 1 mg/m³ |
British Columbia | OEL TWA (mg/m³) | 0.2 mg/m³ (Thoracic, contained in strong inorganic acid mists) |
Manitoba | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
New Brunswick | OEL STEL (mg/m³) | 3 mg/m³ |
New Brunswick | OEL TWA (mg/m³) | 1 mg/m³ |
Newfoundland & Labrador | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
Nova Scotia | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
Nunavut | OEL STEL (mg/m³) | 3 mg/m³ |
Nunavut | OEL TWA (mg/m³) | 1 mg/m³ |
Northwest Territories | OEL STEL (mg/m³) | 3 mg/m³ |
Northwest Territories | OEL TWA (mg/m³) | 1 mg/m³ |
Ontario | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic) |
Prince Edward Island | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
Québec | VECD (mg/m³) | 3 mg/m³ |
Québec | VEMP (mg/m³) | 1 mg/m³ |
Saskatchewan | OEL STEL (mg/m³) | 0.6 mg/m³ (thoracic fraction) |
Saskatchewan | OEL TWA (mg/m³) | 0.2 mg/m³ (thoracic fraction) |
Yukon | OEL STEL (mg/m³) | 1 mg/m³ |
Yukon | OEL TWA (mg/m³) | 1 mg/m³ |
8.2. Exposure Controls
Appropriate Engineering Controls: Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Personal Protective Equipment: Avoid all unnecessary exposure. Protective clothing. Gloves. Insufficient ventilation: wear respiratory protection. Protective goggles.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Impermeable protective gloves.
Eye Protection: A full face shield is recommended. Chemical safety goggles.
Skin and Body Protection: Chemical resistant suit. Rubber apron, boots.
Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits.
Environmental Exposure Controls: Do not allow the product to be released into the environment.
Consumer Exposure Controls: Do not eat, drink or smoke during use.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |
Liquid |
Appearance |
Light red solution |
Odor |
Slight acid odor |
Odor Threshold |
Not available |
pH |
1.2 |
Evaporation Rate |
Not available |
Melting Point |
Not available |
Freezing Point |
Not available |
Boiling Point |
Not available |
Flash Point |
Not available |
Auto-ignition Temperature |
Not available |
Decomposition Temperature |
Not available |
Flammability (solid, gas) |
Not available |
Lower Flammable Limit |
Not available |
Upper Flammable Limit |
Not available |
Vapor Pressure |
Not available |
Relative Vapor Density at 20 °C |
Not available |
Relative Density |
Not available |
Specific Gravity |
1.01 |
Solubility |
Not available |
Partition Coefficient: N-octanol/water |
Not available |
Viscosity |
Not available |
Explosive Properties |
Product is not explosive |
Explosion Data – Sensitivity to Mechanical Impact |
Not expected to present an explosion hazard due to mechanical impact |
Explosion Data – Sensitivity to Static Discharge |
Not expected to present an explosion hazard due to static discharge |
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.
10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, open flames, sources of ignition and incompatible materials.
10.5. Incompatible Materials: Water, humidity. Alkaline solutions. Metals. Oxidizers. Reducing agents. Combustible materials.
10.6. Hazardous Decomposition Products: Corrosive vapors. Sulfuric acid will release sulfur oxides at high temperatures. Sulfur oxides are toxic.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects - Product
Acute Toxicity: Not classified
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Causes skin irritation.
pH: 1.2
Serious Eye Damage/Irritation: Causes serious eye irritation.
pH: 1.2
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: May cause cancer (Inhalation).
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Contact may cause immediate severe irritation progressing quickly to chemical burns. May cause pulmonary edema. Symptoms may be delayed.
Symptoms/Injuries After Skin Contact: Causes skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Swallowing a small quantity of this material will result in serious health hazard.
Chronic Symptoms: Strong inorganic acid mists containing sulfuric acid are carcinogenic to humans. May cause cancer by inhalation.
11.2. Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
Sulfuric acid (7664-93-9)
LD50 Oral Rat |
2140 mg/kg |
LC50 Inhalation Rat |
510 mg/m³ (Exposure time: 2 h) |
Sulfuric acid (7664-93-9) |
|
IARC Group |
1 |
SECTION 12: ECOLOGICAL INFORMATION
12.1. |
Toxicity |
|
Sulfuric acid (7664-93-9) |
|
|
LC50 Fish 1 |
500 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static]) |
|
LC 50 Fish 2 |
42 mg/l (Exposure time: 96 h - Species: Gambusia affinis [static]) |
|
12.2. |
Persistence and Degradability |
|
Not available |
|
|
12.3. |
Bioaccumulative Potential |
|
Sulfuric acid (7664-93-9) |
|
|
BCF Fish 1 |
(no bioaccumulation) |
|
12.4. |
Mobility in Soil |
|
Not available
12.5. Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Sewage Disposal Recommendations: Do not dispose of waste into sewer. Do not empty into drains; dispose of this material and its container in a safe way.
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations.
SECTION 14: TRANSPORT INFORMATION
14.1. |
In Accordance with DOT |
Not regulated for transport |
14.2. |
In Accordance with IMDG |
Not regulated for transport |
14.3. |
In Accordance with IATA |
Not regulated for transport |
14.4. |
In Accordance with TDG |
Not regulated for transport |
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
Surface Activator Solution / Acid Dip Solution | |
SARA Section 311/312 Hazard Classes | Immediate (acute) health hazard Delayed (chronic) health hazard |
Water (7732-18-5) | |
Listed on the United States TSCA (Toxic Substances Control Act) inventory | |
Sulfuric acid (7664-93-9) | |
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 Listed on United States SARA Section 313 |
|
SARA Section 302 Threshold Planning Quantity (TPQ) | 1000 |
SARA Section 313 - Emission Reporting | 1.0 % (acid aerosols including mists, vapors, gas, fog, and other airborne forms of any particle size) |
15.2. US State Regulations
Sulfuric acid (7664-93-9) | |
U.S. - California - Proposition 65 - Carcinogens List | WARNING: This product contains chemicals known to the State of California to cause cancer. |
Strong inorganic acid mists containing sulfuric acid (RR-03978-1) | |
U.S. - California - Proposition 65 - Carcinogens List | WARNING: This product contains chemicals known to the State of California to cause cancer. |
Sulfuric acid (7664-93-9) | |
U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List |
15.3. Canadian Regulations
Surface Activator Solution / Acid Dip Solution | |
WHMIS Classification | Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class E - Corrosive Material |
Water (7732-18-5) | |
Listed on the Canadian DSL (Domestic Substances List) | |
WHMIS Classification | Uncontrolled product according to WHMIS classification criteria |
Sulfuric acid (7664-93-9) | |
Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) |
|
IDL Concentration 1 % | |
WHMIS Classification | Class E - Corrosive Material Class D Division 2 Subdivision A - Very toxic material causing other toxic effects |
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 10/23/2014
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
Aquatic Acute 3 | Hazardous to the aquatic environment - Acute Hazard Category 3 |
Carc. 1A | Carcinogenicity Category 1A |
Eye Dam. 1 | Serious eye damage/eye irritation Category 1 |
Eye Irrit. 2A | Serious eye damage/eye irritation Category 2A |
Skin Corr. 1A | Skin corrosion/irritation Category 1A |
Skin Irrit. 2 | Skin corrosion/irritation Category 2 |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H350 | May cause cancer |
H402 | Harmful to aquatic life |
Party Responsible for the Preparation of This Document
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
North America GHS US 2012 & WHMIS