SDS - 24K Bright Gold Solution

Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Revision Date: 02/15/2016 Date of issue: 02/15/2016 Supersedes Date: 04/30/2007 Version: 1.0
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Mixture
Product Name: 24K Bright Gold Solution, 24K Bright Gold Replenisher, 18K Bright Gold Solution, 14K Bright Gold Solution
1.2. Intended Use of the Product
Use of the Substance/Mixture: Electroplating solution.
1.3. Name, Address, and Telephone of the Responsible Party
Company
Gold Plating Services
378 North Main #112 Layton, UT 84041
T: (801) 546 6200
www.gold-plating.com
1.4. Emergency Telephone Number
Emergency Number : PERS (801) 629-0667 or (800) 633-8253
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US classification
Acute Tox. 4 (Oral) H302
Acute Tox. 4 (Dermal) H312
Eye Irrit. 2A H319
Resp. Sens. 1 H334
Skin Sens. 1 H317
Muta. 2 H341
Carc. 2 H351
Repr. 1A H360
Aquatic Acute 3 H402
Aquatic Chronic 3 H412

 

Full text of H-phrases: see section 16
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)
hazard pictogram
Signal Word (GHS-US) : Danger
Hazard Statements (GHS-US) :           H302+H312 - Harmful if swallowed or in contact with skin.
                                                             H317 - May cause an allergic skin reaction.
                                                             H319 - Causes serious eye irritation
                                                             H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
                                                             H341 - Suspected of causing genetic defects.
                                                             H351 - Suspected of causing cancer.
                                                             H360 - May damage fertility or the unborn child.
                                                             H402 - Harmful to aquatic life.
                                                             H412 - Harmful to aquatic life with long lasting
effects.
Precautionary Statements (GHS-US) : P201 - Obtain special instructions before use.
                                                             P202 - Do not handle until all safety precautions have been read and understood.
                                                             P261 - Avoid breathing vapors, mist, or spray.
                                                             P264 - Wash hands, forearms and face thoroughly after handling.
                                                             P270 - Do not eat, drink or smoke when using this product.
                                                             P272 - Contaminated work clothing must not be allowed out of the workplace.
                                                             P273 - Avoid release to the environment.
                                                             P280 - Wear protective gloves, eye protection, face protection, protective clothing.
                                                             P284 - In case of inadequate ventilation wear respiratory protection.
                                                             P301+P330+P312 - If swallowed: Rinse mouth. Call a poison center or doctor if you feel unwell.
                                                             P302+P352+P362+P364 - If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse.
                                                             P304+P340 - If inhaled: Remove person to fresh air and keep at rest in a position comfortable for breathing.
                                                             P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes.
                                                             Remove contact lenses, if present and easy to do. Continue rinsing.
                                                             P308+P313 - If exposed or concerned: Get medical advice/attention.
                                                             P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
                                                             P337+P313 - If eye irritation persists: Get medical advice/attention.
                                                             P342+P311 - If experiencing respiratory symptoms: Call a poison center or doctor
                                                              P405 - Store locked up.
                                                              P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations.
2.3. Other Hazards
Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Not applicable
3.2. Mixture
Name Product Identifier % GHS-US classification
Water (CAS No) 7732-18-5 82.9 Not classified
Citric acid (CAS No) 77-92-9 12.5 Comb. Dust, H232
Eye Irrit. 2A, H319
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, tripotassium salt (CAS No) 866-84-2 2.3 Not classified
Cobaltate(2-), [[N,N'-1,2-ethanediylbis[N-(carboxymethyl) glycinato]](4-)-N,N',O,O',ON,ON']-, (OC-6-21)- (CAS No) 14931-83-0 1 Acute Tox. 4 (Oral), H302
Resp. Sens. 1, H334
Skin Sens. 1, H317
Muta. 2, H341
Repr. 1A, H360
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Phosphoric acid, potassium salt (1:1) (CAS No) 7778-77-0 0.8 Not classified
Aurate(1-), bis(cyano-C)-, potassium (CAS No) 13967-50-5 0.4 Acute Tox. 2 (Oral), H300
Acute Tox. 1 (Dermal), H310
Acute Tox. 2 (Inhalation), H330
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Nickelate(1-), [N,N-bis(carboxymethyl)glycinato(3-)- N,O,O',O'']-, hydrogen, (T-4)- (CAS No) 34831-03-3 0.1 Acute Tox. 4 (Oral), H302
Resp. Sens. 1, H334
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
First-aid Measures After Inhalation: Keep at rest and in a position comfortable for breathing. Seek medical attention. Symptoms may be delayed.
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water or soap and water for at least 15 minutes. Wash contaminated clothing before reuse. Obtain medical attention if irritation develops or persists.
First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Obtain medical attention if irritation persists.
First-aid Measures After Ingestion: Rinse mouth thoroughly with water. Do NOT induce vomiting. Seek medical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Harmful if swallowed or in contact with skin. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause cancer (oral and dermal). Suspected of causing genetic defects. May damage fertility or the unborn child. Causes serious eye irritation.
Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms may include: Sore throat. Cough. Burning sensation.
Symptoms/Injuries After Skin Contact: Harmful in contact with skin. May cause an allergic skin reaction. Symptoms may include: Redness, pain, swelling, itching, burning, dryness, and dermatitis.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision.
Symptoms/Injuries After Ingestion: Harmful if swallowed. Symptoms may include: Gastrointestinal irritation. Abdominal pain. Diarrhea. Nausea. Vomiting.
Chronic Symptoms: Suspected of causing genetic defects. May damage fertility or the unborn child. Suspected of causing cancer (oral and dermal).
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If you feel unwell, seek medical advice (show the label where possible).
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable
Reactivity: Hazardous reactions will not occur under normal conditions.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present.
Firefighting Instructions: Use water spray or fog for cooling exposed containers.
Protection During Firefighting: Firefighters must use full bunker gear including NIOSH-approved positive-pressure self-contained breathing apparatus to protect against potential hazardous combustion and decomposition products.
Other Information: Do not allow the product to be released into the environment.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor, mist or spray.
6.1.1. For Non-emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel. Keep upwind.
6.1.2. For Emergency Responders
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
6.2. Environmental Precautions
Avoid release to the environment.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Small quantities of liquid spill: take up in noncombustible absorbent material and shovel into container for disposal. Collect absorbed material and place into a sealed, labeled container for proper disposal. Practice good housekeeping - spillage can be slippery on smooth surface either wet or dry.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Precautions for Safe Handling: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Always wash your hands immediately after handling this product, and once again before leaving the workplace. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke in areas where product is used.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Observe all regulations and local requirements regarding storage of containers
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store locked up.
Incompatible Products: Strong acids.
7.3. Specific End Use(s)
Electroplating solution.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).
8.2. Exposure Controls
Appropriate Engineering Controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed.
Personal Protective Equipment : Protective clothing. Gloves. Protective goggles. Insufficient ventilation: wear respiratory protection.
Personal Protective Equipment
Materials for Protective Clothing : Chemically resistant materials and fabrics.
Hand Protection : Wear chemically resistant protective gloves.
Eye Protection : Chemical safety goggles.
Skin and Body Protection : Wear appropriate personal protective equipment.
Respiratory Protection : Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits.
Environmental Exposure Controls : Do not allow the product to be released into the environment.
Consumer Exposure Controls : Do not eat, drink or smoke during use.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State                                    : Liquid
Appearance                                        : Purple liquid
Odor                                                    : Odorless
Odor Threshold                                  : No data available
pH                                                        : 4.5 - 5
Evaporation Rate                               : No data available
Melting Point                                      : No data available
Freezing Point                                    : ≈ 30 °F (-1.11 °C) at standard pressure
Boiling Point                                       : No data available
Flash Point                                          : No data available
Auto-ignition Temperature                : No data available
Decomposition Temperature            : No data available
Flammability (solid, gas)                   : No data available
Vapor Pressure                                   : No data available
Relative Vapor Density at 20 °C        : No data available
Relative Density                                  : No data available
Specific Gravity                                   : 1.1 g/cm³
Solubility                                              : Water: Soluble
Partition Coefficient: N-Octanol/Water : No data available
Viscosity                                               : No data available
Explosive Properties                           : Product is not explosive.
9.2. Other Information No additional information available
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Hazardous reactions will not occur under normal conditions.

10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).

10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.

10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, open flames, sources of ignition and incompatible materials.

10.5. Incompatible Materials: Strong acids.

10.6. Hazardous Decomposition Products: Hydrogen cyanide.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information On Toxicological Effects
Acute Toxicity: Oral: Harmful if swallowed. Dermal: Harmful in contact with skin.
24K Bright Gold Solution  
ATE (Oral) 1,216.55 mg/kg body weight
ATE (Dermal) 1,250.00 mg/kg body weight
Cobaltate(2-), [[N,N'-1,2-ethanediylbis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']-, (OC-6-21)- (14931-83-0)
ATE (Oral) 500.00 mg/kg body weight
Nickelate(1-), [N,N-bis(carboxymethyl)glycinato(3-)-N,O,O',O'']-, hydrogen, (T-4)- (34831-03-3)
ATE (Oral) 500.00 mg/kg body weight
Citric acid (77-92-9)  
LD50 Oral Rat 5400 mg/kg
LD50 Dermal Rat > 2000 mg/kg
Aurate(1-), bis(cyano-C)-, potassium (13967-50-5)
ATE (Oral) 5.00 mg/kg body weight
ATE (Dermal) 5.00 mg/kg body weight
ATE (Gases) 100.00 ppmV/4h
ATE (Vapors) 0.50 mg/l/4h
ATE (Dust/Mist) 0.05 mg/l/4h
Skin Corrosion/Irritation: Not classified
pH: 4.5 - 5
Serious Eye Damage/Irritation: Causes serious eye irritation.
pH: 4.5 - 5
Respiratory or Skin Sensitization: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction.
Germ Cell Mutagenicity: Suspected of causing genetic defects.
Carcinogenicity: Suspected of causing cancer.
Reproductive Toxicity: May damage fertility or the unborn child.
Specific Target Organ Toxicity (Single Exposure): Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms may include: Sore throat. Cough. Burning sensation.
Symptoms/Injuries After Skin Contact: Harmful in contact with skin. May cause an allergic skin reaction. Symptoms may include: Redness, pain, swelling, itching, burning, dryness, and dermatitis.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching,burning, tearing, and blurred vision.
Symptoms/Injuries After Ingestion: Harmful if swallowed. Symptoms may include: Gastrointestinal irritation. Abdominal pain.Diarrhea. Nausea. Vomiting.
Chronic Symptoms: Suspected of causing genetic defects. May damage fertility or the unborn child. Suspected of causing cancer
(oral and dermal).
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Ecology - General : Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Citric acid (77-92-9)  
LC50 Fish 1 1516 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
12.2. Persistence and Degradability
Citric acid (77-92-9)  
Persistence and Degradability Readily biodegradable in water.
12.3. Bioaccumulative Potential
Citric acid (77-92-9)  
Log Pow -1.72 (at 20 °C)
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
Other Information : Avoid release to the environment. 
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Sewage Disposal Recommendations: This material is hazardous to the aquatic environment. Keep out of sewers and waterways.
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations
SECTION 14: TRANSPORT INFORMATION
14.1. In Accordance with DOT Not regulated for transport
14.2. In Accordance with IMDG Not regulated for transport
14.3. In Accordance with IATA Not regulated for transport
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
24K Bright Gold Solution
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
Water (7732-18-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Cobaltate(2-), [[N,N'-1,2-ethanediylbis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']-, (OC-6-21)- (14931-83-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Nickelate(1-), [N,N-bis(carboxymethyl)glycinato(3-)-N,O,O',O'']-, hydrogen, (T-4)- (34831-03-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, tripotassium salt (866-84-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Citric acid (77-92-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Phosphoric acid, potassium salt (1:1) (7778-77-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Aurate(1-), bis(cyano-C)-, potassium (13967-50-5)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2 US State Regulations Neither this product nor its chemical components appear on any US state lists.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 02/15/2016
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
- Acute Tox. 1 (Dermal) Acute toxicity (dermal) Category 1
Acute Tox. 2 (Inhalation) Acute toxicity (inhalation) Category 2
Acute Tox. 2 (Oral) Acute toxicity (oral) Category 2
Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3
Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1
Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3
Carc. 2 Carcinogenicity Category 2
Comb. Dust Combustible Dust
Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
Muta. 2 Germ cell mutagenicity Category 2
Repr. 1A Reproductive toxicity Category 1A
Resp. Sens. 1 Respiratory sensitisation Category 1
Skin Sens. 1 Skin sensitization Category 1
H232 May form combustible dust concentrations in air
H300 Fatal if swallowed
H302 Harmful if swallowed
H310 Fatal in contact with skin
H312 Harmful in contact with skin
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H330 Fatal if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer
H360 May damage fertility or the unborn child
H400 Very toxic to aquatic life
H402 Harmful to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
SDS US (GHS HazCom)