SAFETY DATA SHEET

SECTION 1: IDENTIFICATION

Product Name: Rose Gold Plating Solution
Other Means of Identification: Rose Gold Brush Plating Solution, Rose Gold Bath Plating Solution

Intended Use of the Product: Electroplating bath and brush
Restrictions on Use: For professional use only

Name, Address, and Telephone of the Responsible Party
Distributor:
Gold Plating Services 
378 North Main #112 Layton, UT 84041
T: (801) 546 6200 
www.GoldPlating.com

Emergency Telephone Number
PERS (801) 629-0667 or (800) 633-8253


SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture 

REGULATION

CLASSIFICATION

OSHA HAZARD COMMUNICATION

Skin corrosion (Category 2); Serious eye damage (Category 1); Acute Toxicity, Oral (Category 3); Acute Toxicity, Dermal (Category 3); Acute Toxicity, Inhalation (Category 4); Acute aquatic toxicity (Category 3)

REACH/CLP 

Skin corrosion (Category 2); Serious eye damage (Category 1); Acute Toxicity, Oral (Category 3); Acute Toxicity, Dermal (Category 3); Acute Toxicity, Inhalation (Category4)

EU DIRECTIVES 67/548/EEC; 1999/45/EC

Corrosive. Toxic. Dangerous for the Environment [C, T, N]


Label Elements
Hazard Pictograms:

Signal Word:
Danger

Hazard Statements:
Toxic if swallowed or in contact with skin.
Causes skin irritation.
Causes serious eye damage.
Harmful if inhaled.
Harmful to aquatic life.

Precautionary Statements:
Keep out of reach of children.
Avoid breathing mist, vapors, or spray.
Wash thoroughly after handling.
Do not eat, smoke, or drink when using this product.
Use in well-ventilated areas.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: immediately call a POISON CENTER or doctor/physician. Rinse mouth.
IF ON SKIN (or hair): take off all contaminated clothing immediately. Rinse skin with water/shower.
IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing
IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
Call a POISON CENTER/doctor/physician if you feel unwell.
Specific treatment (see Antidote on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container to an approved waste disposal plant; precious metal reclamation should be considered.

Antidote:
If breathing is difficult or victim is unconscious, administer amyl nitrite.

Other Hazards
Physical Description: This product is light yellow with a slight, almond-like odor.
Health Hazards: This product is severely irritating to exposed tissue. This solution is poisonous; ingestion in small quantities can be fatal. Additionally, inhalation over-exposures may be harmful or fatal. Skin contact may cause severe irritation or tissue damage, especially upon prolonged exposure.
Fire Hazards: This product is not reactive or flammable under normal conditions.
 Physical Hazards: If heated to decomposition, this solution may produce toxic vapors containing hydrogen cyanide and sodium and potassium compounds.
 Environmental Hazards: This product may be harmful or fatal to contaminated terrestrial and aquatic life-forms.

Unknown Acute Toxicity
Not applicable


SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Mixture:

COMPONENT

CAS NUMBER

EINECS #

EC Class/Risk Phrases

% (w/w)

Sodium Cyanide

143-33-9

205-599-4

Not Established

< 2

Gold

7440-57-5

231-169-5

Not Established

< 1

Potassium Cyanide

151-50-8

205-792-3

Not Established

< 1

Sodium Hydroxide (formed in solution along with small amounts of Gold Cyanide Complex)

1310-73-2

215-185-5

Risk: C (Corrosive)
R35: Causes severe burns.

< 1

Water and other components - Each of the other components is present in less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens) and EC Class/Risk Phrases are not established.


SECTION 4: FIRST AID MEASURES

Description of First Aid Measures
After Inhalation: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions.
After Skin Contact: Flush area with warm, running water for 15 minutes.
After Eye Contact: Flush with copious amounts of water for 15 minutes. Roll eyes during flush. Seek medical attention immediately.
After Ingestion: Contact a Poison Control Center or physician for instructions. If professional advice is not available, do not induce vomiting. Victim should drink milk, egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow.

Most Important Symptoms and Effects, Both Acute and Delayed
After Inhalation: Over-exposure to mists or sprays of this product by inhalation may cause irritation of the nose, throat, and respiratory tract. Inhalation over-exposures to this product can also cause cyanide poisoning. Symptoms of such poisoning can include weakness, headache, confusion, nausea, vomiting, convulsions, coma, and possibly death.
After Skin Contact: Sodium Cyanide and Potassium Cyanide (components of this product) can be absorbed through the skin. Symptoms of such over-exposure will include those described for “Inhalation.” Repeated or prolonged over-exposures can be fatal. Brief contact with the skin is irritating; repeated or prolonged skin contact can cause dermatitis (i.e. red, inflamed skin) and “Cyanide Rash” (i.e. itching, macular, papular, and vesicular eruptions). Sodium Cyanide and Potassium Cyanide (components of this product), are sensitizers and can cause the development of allergy-like skin reactions (i.e. rashes and welts).
After Eye Contact: If splashed into the eyes, the solution will cause immediate irritation. Symptoms of such overexposure include discomfort, tearing, and blurring of vision. Repeated or prolonged exposures of this product with the eyes can also cause corneal opacity (clouding of the surface of the eye) and possibly permanent eye injury.
After Ingestion: Though not anticipated to be a significant route of occupational exposure, ingestion of this product, even in small quantities, can be fatal. The symptoms of cyanide poisoning are described under “Inhalation.”
Chronic Symptoms: Chronic over-exposures to this solution can cause dermatitis (inflammation of the skin) after prolonged or repeated skin contact and may damage optic nerves. Sodium Cyanide and Potassium Cyanide are sensitizers and can cause the development of allergy-like reactions.
Target Organs: Skin, eyes, respiratory system, blood, and metabolic enzymes.

Indication of Any Immediate Medical Attention and Special Treatment Needed
Recommendations to Physicians: Treat symptoms and eliminate exposure.
Cyanide Exposure Preparedness: All persons working with this product should be aware of the potential for cyanide poisoning and trained to provide first aid using oxygen and amyl nitrite. Always have on-hand the materials needed. Actions to be taken in case of cyanide poisoning should be planned and practiced before beginning work with cyanides. Identification of community hospital resources and emergency medical assistance in order that they be equipped and trained on the handling of cyanide emergencies is essential.
Antidote: If the victim has difficulty breathing, is becoming confused, and/or is losing consciousness, administer amyl nitrite. The following procedure is recommended: Crush one pearl of amyl nitrite onto a cloth and hold to the victim’s nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times, using a new pearl every 5 minutes (0.3 mg size) or every 3 minutes (0.18 mg size) until patient regains consciousness. While amyl nitrite is being used, monitor the victim’s blood pressure. If it drops below 80/60, stop the amyl nitrite and obtain the opinion of a physician immediately. If breathing has stopped, trained personnel should begin artificial respiration or, if the heart has stopped, begin cardiopulmonary resuscitation (CPR) immediately (avoid mouth to mouth contact). If breathing is difficult, oxygen (preferably 100 percent) may be helpful. Quickly transport victim to an emergency facility. Physicians should refer to Section 11 (Toxicology Information) for additional information.
Medical Conditions Aggravated by Overexposure: Over-exposure to this product may aggravate pre-existing respiratory, blood, and skin conditions.


SECTION 5: FIRE-FIGHTING MEASURES

Suitable Extinguishing Media
Water spray, water jet, dry powder, foam, carbon dioxide, halon, or any other.

Unsuitable Extinguishing Media
None known

Specific Hazards Arising From the Substance or Mixture
NFPA Flammability Classification: Not flammable
Unusual Hazards In Fire Situations: Due to the presence of cyanide compounds, this solution presents a significant health hazard to fire-fighters. When involved in a fire, this material may decompose and produce irritating fumes and toxic gasses (e.g., hydrogen cyanide and potassium and sodium compounds).
Sensitivity to Mechanical Impact: Not sensitive
Explosion Sensitivity to Static Discharge: Not sensitive

Advice for Firefighters
Precautionary Measures: Move containers from fire area if it can be done without risk to personnel. Otherwise, use water spray to keep fire-exposed containers cool. Contaminated equipment should be rinsed with a 10% bleach solution, then thoroughly rinsed with water, before returning to service.
Protection During Firefighting: Wear self-contained breathing apparatus and full protective equipment for fire response.


SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures
Response to Incidental Releases:
Personnel who have received basic chemical safety training can generally handle small-scale releases (e.g., under 1 gallon). For small releases, the minimum Personal Protective Equipment should be rubber gloves and rubber apron, splash goggles, or safety glasses. In the event of a release situation during which there is a potential for inhalation of mists or sprays, respiratory protection should be worn. If necessary, use an air-purifying respirator with high-efficiency particulate filter cartridges with face-shield. Use caution during clean-up; contaminated floors and items may be slippery.
Response to Non-Incidental Releases:
If oxygen levels are below 19.5% or are unknown, or if the release is deemed non-incidental, clear the affected area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemically resistant suit and boots, hard-hat, and Self Contained Breathing Apparatus (SCBA). SCBA should be worn when oxygen levels are below 19.5% or are unknown.

Environmental Precautions
Avoid response actions that can cause a release of a significant amount of the substance (1 liter or more) into the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

Methods and Material for Containment and Cleaning Up
Absorb spilled liquid with polypads or other suitable absorbent materials. Treat any potentially contaminated item or surface with 10 percent bleach solution followed by a triple rinse with water.


SECTION 7: HANDLING AND STORAGE

Precautions for Safe Handling
Keep out of reach of children. Follow good chemical hygiene practices. Do not smoke, drink, eat, or apply cosmetics in the chemical use area. Avoid inhalation of vapors, mists, and sprays. Use in well-ventilated areas. Avoid contact with skin or eyes. Remove contaminated clothing promptly. Clean up spilled product immediately. Medical treatment kits for cyanide poisoning should be conveniently
 located for easy access. Employees must be appropriately trained to use this product safely as needed. Keep containers closed when not in use.

Conditions for Safe Storage, Including Any Incompatibilities
Ensure all containers are correctly labeled. Store containers away from direct sunlight, sources of intense heat, or where freezing is possible. Store this product away from incompatible chemicals (See Section 10, Stability and Reactivity). Empty containers may contain residual liquid; therefore, empty containers
 should be handled with care. Material should be stored in secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials. Storage areas should be made of corrosion-resistant materials. If appropriate, post warning signs in storage and use areas. Inspect
 all incoming containers before storage to ensure containers are properly labeled and not damaged.


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits
U.S. National Exposure Limits:

COMPONENT

ACGIH TLV

OSHA PEL

NIOSH REL

OTHER

Sodium Cyanide , Potassium Cyanide, (Cyanides, as CN)

5 mg/m3, Ceiling (as Cyanide Salts); Skin

TWA - 5 mg/m3 ;Skin

NE

NE

Gold

NE

NE

NE

NE

Sodium Hydroxide

2 mg/m3, Ceiling

TWA - 2 mg/m3

2 mg/m3, Ceiling

NE


International Exposure Limits:

COMPONENT

Federal Republic of Germany (DFG)
Maximum Concentration Values in
 the Workplace (MAKs)

OTHER

Sodium Cyanide , Potassium
Cyanide, (Cyanides, as CN)

United Kingdom Workplace Exposure Limits:
TWA = 5mg/m3, Skin

United Kingdom Workplace Exposure
Limits: TWA = 5mg/m3, Skin

Gold

NE

NE

Sodium Hydroxide

NE

United Kingdom Workplace Exposure
Limits: STEL = 2mg/m3


Biological Occupational Exposure Limits: None available for the components of this product.
Derived No Effect Level (DNEL): Not established
Predicted No Effect Concentration (PNEC): Not established

Appropriate Engineering Controls
Use this product in a well-ventilated environment. Safety showers, eye wash stations, and hand-washing equipment should be available.

Personal Protective Equipment
Hand Protection:
Rubber or neoprene gloves should be used. Use triple gloves for spill response.
Eye Protection:
Splash goggles or safety glasses. If more than 1 gallon of this product is to be used, a face shield should be considered.
Skin and Body Protection:
Use a body protection appropriate to task (e.g., lab coat, coveralls, or apron). Care should be taken to select protection for potentially exposed areas when splashes, sprays, or prolonged exposure could occur in occupational settings.
Respiratory Protection:
None needed under normal conditions of use. Use NIOSH approved respirators if ventilation is inadequate to control mists. Maintain airborne contaminate concentrations below guidelines listed in Section 3. The following is the NIOSH Respiratory Guideline Protection Equipment recommendations for Sodium Cyanide:

  • Up to 25 mg/m - Supplied Air Respirator 3 or full facepiece Self Contained Breathing Apparatus.
  • Emergency or Planned Entry Into Unknown Concentrations or  IDLH Conditions - Positive pressure, full facepiece Self Contained Breathing Apparatus; or positive pressure, full facepiece Supplied Air Respirator with an auxiliary positive pressure Self Contained Breathing Apparatus.
  • Escape - Gas mask with high-efficiency particulate filter and canister to protect against cyanides; or escape type Self Contained Breathing Apparatus.


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Light yellow solution
Odor: Slight, almond-like odor
Odor Threshold: Not determined
Melting Point: Not available
Freezing Point: Not available
Boiling Point: Not available
Flammability (solid, gas): Not flammable
Upper/Lower Explosion Limits: Not applicable
Flash Point: Not applicable
Auto-Ignition Temperature: Not applicable
Decomposition Temperature: Not determined
pH: > 12.10.
Kinematic Viscosity: Not determined
Solubility: Soluble
Partition Coefficient N-Octanol/Water: Not determined
Vapor Pressure: Not determined
Relative Density (water = 1): Approximately 1.0
Relative Vapor Density: Not determined
Particle Characteristics: Not applicable
Evaporation Rate (water = 1): Approximately 1.0


SECTION 10: STABILITY AND REACTIVITY

Reactivity: Not reactive under typical conditions of use or handling; contact
 with water can generate some amount of heat.
Chemical Stability: Normally stable under standard temperatures and pressures.
Possibility of Hazardous Reactions: This product is not self-reactive or air-reactive. This product will not undergo hazardous polymerization.
Conditions to Avoid: Avoid contact with incompatible chemicals.
Incompatible Materials: This product is not compatible with oxidizers or strong acids. Contact of this product with acids or acid salts can release toxic
 hydrogen cyanide gas.
Hazardous Decomposition Products: The products of thermal decomposition include hydrogen cyanide, other cyanide compounds, and substances containing sodium, potassium, and gold.


SECTION 11: TOXICOLOGICAL INFORMATION

Routes of Exposure and Symptoms
 Inhalation: Mists or vapors of this product can cause nasal irritation, sore throat, choking, coughing, and breathing difficulties. 
Skin Contact: May cause moderate to severe skin irritation and chemical burns. Repeated exposure to this material can result in absorption through skin causing significant health hazard.
Eye Contact: May cause moderate to severe eye irritation and chemical burns.
Ingestion: Although not anticipated to be a significant route of occupational over-exposures, ingestion of this product may be fatal.
Note: This product can cause cyanide poisoning by all routes of exposure.

Delayed and Immediate Effects & Chronic Effects from Short and Long Term Exposure
Degree of Irritation: Moderate to severe especially after prolonged exposure.
Sensitization: Sodium Cyanide and Potassium Cyanide (components of this product) are sensitizers and can cause allergy-like skin reactions upon repeated or prolonged exposure.
Reproductive Toxicity: This product is not reported to have adverse reproductive effects in humans. Clinical studies on test animals exposed to relatively high doses of Potassium Cyanide and Sodium Cyanide (a component of this product) indicate adverse reproductive effects.
Mutagenic Effects: This product is not reported to have mutagenic effects in humans. Mutation data are available for Potassium Cyanide and Sodium Cyanide (components of this product); these data were obtained during clinical studies on specific human or animal tissues exposed to high doses of these compounds.
Specific Target Organ Toxicity - Single Exposure and Repeated Exposure: Not classified.

Acute Toxicity Estimates
Sodium Cyanide

LDLo - Oral - Human

2800 ug/kg

LDLo - Oral - Human - man

6557 ug/kg: Behavioral - fluid intake; Gastrointestinal - gastritis

LDLo - Oral - Human

2857 ug/kg

TDLo - Oral - Human - man

714 ug/kg: Behavioral - hallucinations, distorted perceptions; Behavioral - muscle

LDLo - Unreported: Human - man

2206 ug/kg

LD50 - Oral - rat

6440 ug/kg


Potassium Cyanide

LDLO Oral – Human

2.857 mg/kg

LD50 Oral – mouse

8.5 mg/kg

LD50 Oral – rabbit

5 mg/kg

LD50 Oral – rat

6 mg/kg


Interactive Effects
No data available

Carcinogen Listings
IARC: No
NTP: No
OSHA: No 


SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity
Based on available data, this product is anticipated to be harmful or fatal to contaminated terrestrial plants or animals and aquatic plants or animals. It has the potential to significantly raise the pH of the surrounding local water systems. The following aquatic toxicity data are available for components of this product:

Potassium Cyanide

LC50 (Salmo salar atlantic salmon)

24 hours = 0.08-068 mg/L

EC0 (Salmo gairdneria rainbow trout)

40 minutes = 0.001 mg/L

TLm (bluegill)

48 hours = 0.16 ppm

TLm (zebrafish)

48 hours = 0.49 ppm


Sodium Cyanide

TLm (bluegill)

96 hours = 0.15 ppm

50LC (prawn)

48 hours = 0.25 ppm

LC50 (Pimephales promelas fathead minnow)

96 hours = 0.32 mg/L

LC50 (Salmo gairdneri rainbow trout fry)

96 hours = 0.0521-0.0748 mg/L

LC50 (Dinophilus gyrociliatus worm)

96 hours = 5.94-7.57 mg/L

LC50 (Daphnia magna giant water flea)

96 hours = 0.17 mg/L

LC50 (Helisoma trivolvis mollusk)

96 hours = > 100 mg/L

LC50 (Gammarus fasciatus crustacean)

96 hours = 1.7 mg/L

LC50 (Lumbriculus variegatus worm)

96 hours = 21 mg/L


Persistence and Degradability
When released into the soil, the components of this product are expected to dissipate in soils via oxidation, or otherwise chemically degrade or photo-decompose via solar radiation.

Bioaccumulative Potential
The following components of this product are not reported to bioaccumulate significantly.

Mobility in Soil
 It is to be expected this product will have small mobility in soil. Some of the components may get into the soil and, ultimately, the ground water. Product spreads on the water surface.

Other Adverse Effects
No component is reported to be an endocrine disruptor.


SECTION 13: DISPOSAL CONSIDERATIONS

Waste Handling Recommendations: Prepare, transport, treat, store, and dispose of waste product according to all applicable local, U.S. State, and U.S. Federal regulations, the applicable Canadian standards, or the appropriate
 standards of the nations of the European Community.
Precious Metal Reclamation: Users of the product may wish to utilize precious metal reclamation services for final disposition of wastes.
EPA RCRA Waste Code: D002; P030
European Waste Code: 11 03 01, Wastes Containing Cyanide


SECTION 14: TRANSPORT INFORMATION

In Accordance with IATA
 This product is regulated as dangerous goods by the International Air Transport Association. Use the following information:

Proper Shipping Name: Corrosive liquid, toxic, n.o.s. (Sodium Hydroxide, Gold Cyanide)
Passenger & Cargo Aircraft:
Limited Quantity - Packing Instruction: 841 Max. Qty per PKG: 1.0L
Packing Instruction - 852
Max. Qty per PKG - 5L
Cargo Aircraft Only:
Packing Instruction - 856
Max. Qty per PKG - 60L

European Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR)
This product is considered dangerous goods. Use the above information for transport classification.

Environmental Hazards
None described, as related to transportation.

Special Precautions for Users
Not applicable

Transport in Bulk
Not applicable


SECTION 15: REGULATORY INFORMATION

US Federal Regulations
U.S. SARA Threshold Planning Quantity: Sodium Cyanide = 100 lb (45.4 kg),
Potassium Cyanide = 100 lb (45.4 kg)
U.S. SARA Hazard Categories (Section 311/312, 40 CFR 370-21):
Acute: Yes
Chronic: Yes 
Fire: No 
Reactive: No
Sudden Release: No
U.S. CERCLA Reportable Quantity (RQ): Sodium Cyanide = 100 lb (45.4 kg),
Potassium Cyanide = 100 lb (45.4 kg)
U.S. TSCA Inventory Status: All components of this product are listed on the TSCA Inventory.
US SARA 313: This material contains cyanide compounds (Sodium Cyanide, Potassium Cyanide) that are subject to the requirements of SARA Title III and 40 CFR Part 373.

International Regulations
Canadian DSL/NDSL Inventory Status: The listed components of this product are on the DSL/NDSL Inventory.
Canadian Environmental Protection Act (CEPA) Priorities Substances List: The components of this product are not on the CEPA Priorities Substances Lists.
German Water Hazard Classification: 2 (moderate hazard to waters)


SECTION 16: OTHER INFORMATION

Current SDS preparation date: October 22, 2024
Last SDS Preparation Date: January 15, 2022
Original SDS preparation date: May 27, 1999

Other Information
 This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.

Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above-named manufacturer/supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.